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101.
B.Y. Man S.C. XuC. Yang M. LiuS.Z. Jiang Y.Y. MaC.S. Chen A.H. LiuX.G. Gao C.C. WangB. Hu 《Applied Surface Science》2011,257(15):6321-6325
Single-phase β-FeSi2 films on silicon (1 0 0) were fabricated by pulse laser deposition. The structure and crystal quality of the samples were characterized by X-ray diffraction and Fourier transform infrared spectroscopy. The field scanning electron microscopy showed that the film thickness increases with the increasing of the laser fluence. Moreover, atomic force microscopy observations revealed the changes of surface properties with different laser fluence. Based upon all experimental results, it is found that 7 J/cm2 is the most favorable for the formation of β-FeSi2 thin films. 相似文献
102.
E. Cattaruzza M. MardeganE. Trave G. BattaglinP. Calvelli F. EnrichiF. Gonella 《Applied Surface Science》2011,257(12):5434-5438
Glass layers for planar light waveguides prepared by Ag-Na ion exchange of different silicate glasses in molten salt baths are annealed and/or irradiated with a laser beam in the UV region, with different energy density values and total pulse numbers. The samples are mainly characterized by optical absorption spectroscopy, luminescence spectroscopy, and Rutherford backscattering spectrometry, in order to determine the role of irradiation parameters and of the host matrix structure in the aggregation phenomena. Photoluminescence spectroscopy gave information regarding the presence of Ag multimeric aggregates, the primal seeds for the growing (nano)crystals. The appearance of the plasmon resonance band in the optical absorption spectra proved the formation of Ag clusters and allowed the evolution steps of the clusterization process to be followed as a function of the energy deposited during the laser irradiation. 相似文献
103.
A low power density single-pulse laser irradiation of the Si surface has been used for the study of formation and self-organization of silicon nanotips. A two dimensional regular array of hillock-like nanotips has been created in the central region, a disturbed array comprising crossed lines of hillocks in the near-central region, and the “V”-shaped array in the peripheral region. Therefore, the long-range organization of hillocks changes from the center toward the periphery, following the Gaussian-like laser power profile. The evolution of hillocks due to the flow instability of molten silicon is equivalent to the instability of a liquid layer falling down a vertical plate. The novel result is that the hillock-like soliton structures can be identified with the lump solitons resulting from the nonlinear hydrodynamic instability evolution. 相似文献
104.
We defined conditions of the laser-aided formation of nanoporous structures with nanopores ranging in size from 40 to 50 nm using laser pulses of 10.6 μm wavelength at a pulse-repetition rate of up to (4-5)×103 Hz for a model metallic material (a two-component alloy “brass of 62%”). It has been established that the exposure to a uniform laser light at depths of up to 25-30 μm results in the formation of nanopores with a relatively uniform distribution across the surface. The resulting pattern contains both solitary pores and ramified porous channels. The nanopores are uniformly distributed within a subgrain, being fairly stable in size and shape. The nanopore size and shape feature larger non-uniformity on the subgrain boundary. The resulting metallic structures show promise for use as catalysts and ultrafiltration membranes. 相似文献
105.
Wilhelm Pfleging Robert KohlerMaika Torge Vanessa TrouilletFriederike Danneil Michael Stüber 《Applied Surface Science》2011,257(18):7907-7912
A flexible and rapid surface functionalization of amorphous carbon films shows a great potential for various application fields such as biological surfaces and tribological systems. For this purpose, the combination of thin film deposition and subsequent laser material processing was investigated. Amorphous carbon layers doped with hydrogen were deposited on silicon wafers by reactive direct-current magnetron sputtering. Films with three different hydrogen contents were synthesized. Subsequent to the thin film deposition process, UV laser material processing at wavelengths of 193 nm or 248 nm was performed with respect to chemical surface modification and surface structuring on micro- and nanometer scale. Depending on structure size and laser-induced chemical surface modification the adjustment of the surface energy and wetting behaviour in a broad range from hydrophobic to hydrophilic was possible. The chemical modification and the ablation mechanisms near the ablation threshold were strongly influenced by the hydrogen content in amorphous carbon thin films.Structural and chemical information of the as-deposited and modified films was obtained by Raman spectroscopy, X-ray photoelectron spectroscopy and contact angle measurements. 相似文献
106.
T. TaveraN. Pérez A. RodríguezP. Yurrita S.M. OlaizolaE. Castaño 《Applied Surface Science》2011,258(3):1175-1180
The production of periodic structures in silicon wafers by four-beam is presented. Because laser interference ablation is a single-step and cost-effective process, there is a great technological interest in the fabrication of these structures for their use as antireflection surfaces. Three different laser fluences are used to modify the silicon surface (0.8 J cm−2, 1.3 J cm−2, 2.0 J cm−2) creating bumps in the rim of the irradiated area. Laser induced periodic surface structures (LIPSS), in particular micro and nano-ripples, are also observed. Measurements of the reflectivity show a decrease in the reflectance for the samples processed with a laser fluence of 2.0 J cm−2, probably caused by the appearance of the nano-ripples in the structured area, while bumps start to deteriorate. 相似文献
107.
Suiyuan Chen Jing LiangChangsheng Liu Kai SunJyoti Mazumder 《Applied Surface Science》2011,258(4):1443-1450
A high wear-resistant gradient coating made of Ni/Co-based alloys on the surface of a Cu alloy substrate was synthesized using a YAG laser induced in situ reaction method. The coating consists of three layers: the first is a Ni-based alloy layer, the second and third are Co-based alloy layers. The microhardness increases gradually from 98 HV in the Cu alloy substrate to the highest level of 876 HV in the third layer. The main phase of the Co-based alloy layer is CoCr2(Ni,O)4, coexisting with the Fe13Mo2B5, Cr(Co(Mo, and FeCr0.29Ni0.16C0.06 phases. Wear tests indicate that the gradient coating has good bond strength and wear properties with a wear coefficient of 0.31 (0.50 for the Cu alloy substrate). Also, the wear loss of the coating is only 0.01 g after it has been abraded for 60 min, which is only one fifth of that of the Cu alloy of the crystallizer. Wear tests of the gradient coating reveal good adhesive friction and wear properties when sliding against steel under dry conditions. This novel technique may have good application to make an advanced coating on the surface of the Cu alloy crystallizer in a continuous casting process. 相似文献
108.
Wear resistance of reactive plasma sprayed TiB2-TiC0.3N0.7 based composite coatings and the as-sprayed coating with laser surface treatment was investigated using plate-on-plate tests. Wear tests were performed at different normal loads and sliding speeds under dry sliding conditions in air. The surface morphologies of counterparts against as-sprayed and laser remelted coatings were investigated. The microstructure and chemical composition of wear debris and coatings were studied using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), respectively. The results show that the wear resistance of the laser remelted coating is improved significantly due to their increased microhardness and reduced flaws. The primary wear mechanism of the remelted coating is oxidation wear and its minor wear mechanisms are grain abrasion and fatigue failure during the course of wear test. In contrast, the primary wear mechanism of the as-sprayed coating is grain abrasion at the low sliding speed (370 rpm) and fatigue failure at the high sliding speed (549 rpm). The oxidation wear mechanism is a minor contributor for the as-sprayed coating. 相似文献
109.
Surface texturing (for example, producing micro dimples on the surface) of mechanical parts has a great potential to improve the surface tribological properties. Surface texturing through nanosecond laser ablation has many associated advantages and hence has drawn lots of attentions. However, the produced micro dimple bottom (if through laser spot scanning) is often very rough, which may harm the surface tribological properties. In this paper, a two-step laser surface texturing process is proposed and studied, where a relatively high-fluence laser ablation step (which is to create dimples) is followed by a low-fluence laser-induced melting, melted material flow and re-solidification step (which is to smooth the ablated dimple bottom surface). The study shows that the two-step laser surface texturing process can produce dimples with very smooth bottom surfaces. The effects of laser pulse duration and scan speed in Step 2 on the dimple bottom surface morphology and roughness have also been investigated, and some very interesting physical phenomena have been found, which have been rarely reported before in literature. Some hypothesized explanations are given for the observed effects, which require future work to completely understand their underlying mechanisms. 相似文献
110.
Nanosecond (ns) laser ablation can provide a competitive solution for silicon micromachining in many applications. However, most of the previous studies focus on ns lasers at visible or ultraviolet (UV) wavelengths. The research is very limited for ns lasers at infrared (e.g., 1064 nm) wavelengths (which often have the advantage of much lower cost per unit average output power), and the research is even less if the ns laser also has a long pulse duration on the order of ∼100 ns. In this paper, time-resolved observation using an ICCD (intensified charge-coupled device) camera has been performed to understand the physical mechanism of silicon ablation by 200-ns and 1064-nm laser pulses. This kind of work has been rarely reported in the literature. The research shows that for the studied conditions, material removal in laser silicon ablation is realized through surface vaporization followed by liquid ejection that occurs at a delay time of around 200-300 ns. The propagation speed is on the order of ∼1000 m/s for laser-induced plasma (ionized vapor) front, while it is on the order of ∼100 m/s or smaller for the front of ejected liquid. It has also been found that the liquid ejection is very unlikely due to phase explosion, and its exact underlying physical mechanism requires further investigations. 相似文献